Title of article
A formal total synthesis of (±)-9-isocyanoneopupukeanane
Author/Authors
A. Srikrishna، نويسنده , , G. Satyanarayana، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
5
From page
8855
To page
8859
Abstract
A formal total synthesis of the marine sesquiterpene (±)-9-isocyanoneopupukeanane starting from the readily available monoterpene carvone has been accomplished employing a combination of intermolecular Michael addition–intramolecular Michael addition reaction and an intramolecular rhodium carbenoid C–H insertion reaction as key steps, and identifying the isopropenyl group as a masked hydroxy group.
Keywords
Marine sesquiterpenes , Neopupukeanane , Double Michael reaction , Rhodium CH insertion reaction
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1089110
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