• Title of article

    A formal total synthesis of (±)-9-isocyanoneopupukeanane

  • Author/Authors

    A. Srikrishna، نويسنده , , G. Satyanarayana، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    5
  • From page
    8855
  • To page
    8859
  • Abstract
    A formal total synthesis of the marine sesquiterpene (±)-9-isocyanoneopupukeanane starting from the readily available monoterpene carvone has been accomplished employing a combination of intermolecular Michael addition–intramolecular Michael addition reaction and an intramolecular rhodium carbenoid C–H insertion reaction as key steps, and identifying the isopropenyl group as a masked hydroxy group.
  • Keywords
    Marine sesquiterpenes , Neopupukeanane , Double Michael reaction , Rhodium CH insertion reaction
  • Journal title
    Tetrahedron
  • Serial Year
    2005
  • Journal title
    Tetrahedron
  • Record number

    1089110