Title of article :
Iridium-catalyzed enantioselective cycloisomerization of nitrogen-bridged 1,6-enynes to 3-azabicylo[4.1.0]heptenes
Author/Authors :
Takanori Shibata، نويسنده , , Yuka Kobayashi، نويسنده , , Shunsuke Maekawa، نويسنده , , Natsuko Toshida، نويسنده , , Kentaro Takagi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
A cationic iridium complex catalyzes a cycloisomerization of nitrogen-bridged 1,6-enynes to give 3-azabicyclo[4.1.0]heptenes in good to high yield. When an iridium-chiral diphosphine complex is used, the reaction proceeds enantiomerically to give chiral cyclopropanes fused by a six-membered ring system.
Keywords :
enynes , cycloisomerization , Cyclopropanes , Iridium , Enantioselective
Journal title :
Tetrahedron
Journal title :
Tetrahedron
