Author/Authors :
Oscar Navarro، نويسنده , , Nicolas Marion، نويسنده , , Natalie M. Scott، نويسنده , , Juan Gonzalez، نويسنده , , Dino Amoroso، نويسنده , , Andrew Bell، نويسنده , , Steven P. Nolan، نويسنده ,
Abstract :
The synthesis and characterization of two new complexes (IPr)Pd(acac)2 () and (IPr)Pd(acac)Cl () (IPr=(N,Nʹ-bis(2,6-diisopropylphenyl)imidazol)-2-ylidene, acac=acetylacetonate) are described. Complex can be prepared in a one-pot protocol in high yield. A study detailing the versatility of to effectively catalyze a series of cross-coupling reactions is discussed.
Keywords :
Palladium , N-heterocyclic carbenes , Ketone arylation , Aryl amination
