Title of article
Modular chiral selenium-containing oxazolines: synthesis and application in the palladium-catalyzed asymmetric allylic alkylation
Author/Authors
Antônio L. Braga، نويسنده , , Diogo S. Lüdtke، نويسنده , , Jasquer A. Sehnem، نويسنده , , Eduardo E. Alberto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
8
From page
11664
To page
11671
Abstract
A new series of modular chiral selenium-containing oxazolines has been synthesized from inexpensive and commercially available l-serine and l-aspartic acid. These new compounds were evaluated as chiral ligands in the palladium-catalyzed asymmetric allylic alkylation reaction, furnishing the product in high enantiomeric excess, using Cs2CO3/CH2Cl2 as the base/solvent system.
Keywords
Ligands , Oxazolines , Catalyst , Selenium
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1089384
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