Title of article
Stable chiral spirocyclic [5,5]-ammonium ylides using a metallo carbenoid approach
Author/Authors
Daniele Muroni، نويسنده , , Antonio Saba، نويسنده , , Nicola Culeddu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
8
From page
1459
To page
1466
Abstract
Enantiomerically pure spiro[5,5]-ammonium ylides were obtained by Rh(II)-catalyzed decomposition of α-diazo-β-carbonylesters. In the crude decomposition mixtures, variable quantities of enamino-α,β-keto esters were detected as secondary products.
Keywords
rearrangement , diazocompounds , Cascade process , Catalytic decomposition
Journal title
Tetrahedron
Serial Year
2006
Journal title
Tetrahedron
Record number
1089619
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