• Title of article

    Stable chiral spirocyclic [5,5]-ammonium ylides using a metallo carbenoid approach

  • Author/Authors

    Daniele Muroni، نويسنده , , Antonio Saba، نويسنده , , Nicola Culeddu، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2006
  • Pages
    8
  • From page
    1459
  • To page
    1466
  • Abstract
    Enantiomerically pure spiro[5,5]-ammonium ylides were obtained by Rh(II)-catalyzed decomposition of α-diazo-β-carbonylesters. In the crude decomposition mixtures, variable quantities of enamino-α,β-keto esters were detected as secondary products.
  • Keywords
    rearrangement , diazocompounds , Cascade process , Catalytic decomposition
  • Journal title
    Tetrahedron
  • Serial Year
    2006
  • Journal title
    Tetrahedron
  • Record number

    1089619