Title of article :
A new class of chiral pyrrolidine for asymmetric Michael addition reactions. New mechanism via simple 4+2 type attack of the enamine on the trans-nitrostyrene
Author/Authors :
David Diez، نويسنده , , M. Jose Gil، نويسنده , , Rosalina F. Moro، نويسنده , , Isidro S. Marcos، نويسنده , , P. Garc?a، نويسنده , , P. Basabe، نويسنده , , Narciso M. Garrido، نويسنده , , Howard B. Broughton، نويسنده , , J.G Urones، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Pages :
8
From page :
740
To page :
747
Abstract :
A new chiral organocatalyst is described in this paper. A new mechanism for the overall Michael condensation of ketones with nitroolefins using our catalyst is suggested based on molecular modelling studies.
Keywords :
Organocatalysis , proline , Pyrrolidines , Michael addition , transition state , DFT , Cycloaddition 4+2
Journal title :
Tetrahedron
Serial Year :
2007
Journal title :
Tetrahedron
Record number :
1090099
Link To Document :
https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1090099
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