• Title of article

    Alumina-mediated dealkylative dimerization of 4-aminobenzyl esters

  • Author/Authors

    Yu-Ying Lai، نويسنده , , Nai-Ti Lin، نويسنده , , Yi-Hung Liu، نويسنده , , Yu Wang، نويسنده , , Tien-Yau Luh، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2007
  • Pages
    5
  • From page
    6051
  • To page
    6055
  • Abstract
    Treatment of 4-aminobenzyl esters with Al2O3 in DCM at rt afforded the dealkylative dimerized 4,4′-diamino-diphenylmethanes in satisfactory yield. The reaction may proceed via a quinone methide iminium ion intermediate, which may then undergo Michael type addition followed by retro-aldol extrusion of a formaldehyde species.
  • Journal title
    Tetrahedron
  • Serial Year
    2007
  • Journal title
    Tetrahedron
  • Record number

    1091060