Title of article :
Palladium-catalyzed regio- and diastereo-selective allylic alkylation using 2-(diphenylphosphino)benzoic acid: construction of vicinal quaternary and tertiary carbon centers
Author/Authors :
Motoi Kawatsura، نويسنده , , Daiji Ikeda، نويسنده , , Yuji Komatsu، نويسنده , , Kana Mitani، نويسنده , , Takeshi Tanaka، نويسنده , , Junichi Uenishi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
The palladium-catalyzed regio- and diastereo-selective allylic alkylation of allyl acetates with carbon nucleophiles occurred. The stereochemistry was highly controlled by the palladium catalyst with 2-(diphenylphosphino)benzoic acid as the ligand, and vicinal quaternary and tertiary carbon centers were constructed.
Keywords :
Palladium , Catalyst , Regioselectivity , Quaternary carbon center , Diastereoselectivity
Journal title :
Tetrahedron
Journal title :
Tetrahedron
