Title of article
PhI(OAc)2-mediated additions of 2,4-dinitrophenylsulfenamide with methylenecyclopropanes (MCPs) and a methylenecyclobutane (MCB)
Author/Authors
Wei Li، نويسنده , , Min Shi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
11016
To page
11020
Abstract
We report herein stereoselective additions of a nitrene derived from PhI(OAc)2 and 2,4-dinitrophenylsulfenamide with methylenecyclopropanes (MCPs) and a methylenecyclobutane (MCB) to give the corresponding ring enlargement products, (cyclobutylidene)amide or (cyclopentylidene)amide derivatives, in moderate to excellent yields. The reaction mechanism has been discussed on the basis of control experiments and previous investigation.
Keywords
nitrene , 4-Dinitrophenylsulfenamide , Methylenecyclopropanes (MCPs) , Methylenecyclobutane , Stereoselective addition , 2 , PhI(OAc)2
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1093373
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