Author/Authors :
Kazuyuki Sato، نويسنده , , YOSHITAKA ISHIDA، نويسنده , , Eriko Murata، نويسنده , , Yumiko Oida، نويسنده , , Yasumitsu Mori، نويسنده , , Miho Okawa، نويسنده , , Kayoko Iwase، نويسنده , , Atsushi Tarui، نويسنده , , Masaaki Omote، نويسنده , , Itsumaro Kumadaki، نويسنده , , Akira Ando، نويسنده ,
Abstract :
Treatment of α,β-unsaturated ketones and fluoroalkyl halides with Et2Zn in the presence of RhCl(PPh3)3 gave novel reductive fluoroalkylation products at the α-position of α,β-unsaturated ketones in moderate to good yields. The rhodium hydride complex derived from Et2Zn and Rh catalyst seems to have played an important role in this reaction.
Keywords :
Fluorine , fluoroalkyl , Rhodium , ? , ?-Unsaturated ketone , ?-Position
