Title of article
A versatile method for the hydrolysis of gem-dibromomethylarenes bearing carboxylate or boronate group into aldehydes
Author/Authors
John Kallikat Augustine، نويسنده , , Y. Arthoba Naik، نويسنده , , Ashis Baran Mandal، نويسنده , , Nagaraja Chowdappa، نويسنده , , Vinuthan B. Praveen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
8
From page
688
To page
695
Abstract
Hydrolysis of gem-dibromomethylarenes bearing carboxylate or boronate group to corresponding aldehydes without affecting the ester group was successfully accomplished in high yields by subjecting them to refluxing pyridine. Both aromatic and heteroaromatic substrates gave the corresponding aldehydes in good yields. This method was efficiently adapted for the large scale synthesis of 2d and 2f.
Keywords
Boronate , gem-Dibromomethylarene , Bis-pyridinium cation , heteroaromatic , Hydrolytic
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1093659
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