Title of article
6,6′-Bis-substituted BINOL boronic acids as enantioselective and chemoselective fluorescent chemosensors for d-sorbitol
Author/Authors
Xiaofen Liang، نويسنده , , Tony D. James، نويسنده , , Jianzhang Zhao، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
7
From page
1309
To page
1315
Abstract
A new chiral fluorescent BINOL boronic acid 1 has been synthesized. The chiral recognition properties of 1 are drastically different from BINOL boronic acid c. Sensor 1 shows improved enantioselectivity as well as chemoselectivity toward sugar alcohols, such as d-sorbitol and d-mannitol.The enantioselectivity of sensor 1 toward d-sorbitol (KR/KS) is 1:35 (pH 9.0), and the chemoselectivity for d-sorbitol/d-mannitol is 20:1.
Keywords
Enantioselective sensors , Chiral recognition , Sugar alcohols , BINOL boronic acid
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1093721
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