Title of article
Asymmetric electrochemical oxidation of 1,2-diols, aminoalcohols, and aminoaldehydes in the presence of chiral copper catalyst
Author/Authors
Daishirou Minato، نويسنده , , Hitomi Arimoto، نويسنده , , Yoko Nagasue، نويسنده , , Yosuke Demizu، نويسنده , , Osamu Onomura، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
9
From page
6675
To page
6683
Abstract
Asymmetric oxidation of 1,2-diols, aminoalcohols, and aminoaldehydes in the presence of copper(II) triflate and (R,R)-Ph-BOX was accomplished by electrochemical method using Br− as a mediator. This oxidation was applicable to kinetic resolution of racemic cis-cycloalkane-1,2-diols, aminoalcohols, and aminoaldehydes to afford optically active compounds with good to high enantioselectivity.
Keywords
Aminoaldehyde , Asymmetric electrochemical oxidation , Copper complex , 1 , ?-Ketoalcohol , 2-diol , Aminoalcohol
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094304
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