Title of article
Radical 3-exo-tet cyclization of 1,3-dihalopropanes with SmI2 to form cyclopropanes
Author/Authors
Tsuyoshi Ohkita، نويسنده , , Yuhsuke Tsuchiya، نويسنده , , Hideo Togo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
7247
To page
7251
Abstract
The preparation of 1,1-disubstituted and monosubstituted cyclopropanes from corresponding 2,2-disubstituted and 2-monosubstituted 1,3-dihalopropanes, respectively, with SmI2 in THF was efficiently carried out. The reaction mechanism was proposed to proceed in a radical 3-exo-tet manner based on Baldwinʹs rule.
Keywords
3-Dihalopropane , 3-exo-tet , Samariun diiodide , Cyclopropane , Radical , 1
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094368
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