Title of article
Stereoselective synthesis of versatile 2-chloromercurium-3,5-syn-dihydroxy esters via intramolecular oxymercuration
Author/Authors
Carlo Bonini، نويسنده , , Maria Campaniello، نويسنده , , Lucia Chiummiento، نويسنده , , Valeria Videtta، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
7
From page
8766
To page
8772
Abstract
Regio- and stereocontrolled alkoxy mercuration of α,β-unsaturated esters allows direct access to 1,3-syn diols in good yields. Demercuration of adducts leads to 1,3 skipped dihydroxy esters, alcohols, and α-halo esters. The deprotection of acetonide with Amberlyst 15 on 1,3-syn-dihydroxy esters gives the corresponding δ-lactones.
Keywords
Demercuration , Lactonization , Oxymercuration , 1 , 3-syn-Diol
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094554
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