Oligomerization of N-aminodipeptides: to the synthesis of heterogeneous backbone with 1:1 α:α-N-amino aminoacid residue patterns

A large number of N-aminodipeptides compounds have been obtained via a Mitsunobu protocol performed in solution or by solid-phase synthesis. The oligomerization of some of them has been studied in solution or on solid support leading to the formation of 1:1[α:α-N-amino]mers.