Title of article :
Pentamethylcyclopentadienyl ruthenium: an efficient catalyst for the redox isomerization of functionalized allylic alcohols into carbonyl compounds
Author/Authors :
Asmae Bouziane، نويسنده , , Bertrand Carboni، نويسنده , , Christian Bruneau، نويسنده , , François Carreaux، نويسنده , , Jean-Luc Renaud، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
The catalytic activity of the ruthenium(II) complex [RuCp∗(CH3CN)3][PF6] 1 in the transposition of allylic alcohols into carbonyl compounds, in acetonitrile, is reported. This catalyst has proven to be able to catalyze the transformation of poorly reactive and/or functionalized substrates under smooth conditions.
Keywords :
allylic alcohol , Ruthenium , Isomerization
Journal title :
Tetrahedron
Journal title :
Tetrahedron
