Title of article
A straightforward preparation of benzo[f]naphtho[b][1,4]oxazepines from TNT
Author/Authors
Alexander V. Samet، نويسنده , , Konstantine A. Kislyi، نويسنده , , Victor N. Marshalkin، نويسنده , , Yuri A. Strelenko، نويسنده , , Mikhail M. Raihstat، نويسنده , , Yulia V. Nelyubina، نويسنده , , Victor. V. Semenov، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
11763
To page
11767
Abstract
2,4,6-Trinitrotoluene readily reacts with 1-nitroso-2-naphthol to afford 9,11-dinitrobenzo[f]naphtho[2,1-b][1,4]oxazepine. The nitro groups of the latter undergo displacement by O- and S-nucleophiles with preferential substitution of the 11-NO2 (peri-nitro group). The structures of the substitution products are confirmed by X-ray diffraction and 1H NMR NOE experiments.
Keywords
SNAr reactions , 2 , 4 , 6-Trinitrotoluene , 4]oxazepines , 1-Nitroso-2-naphthol
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094911
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