Author/Authors :
Anton Blencowe، نويسنده , , Angela Maria Celli، نويسنده , , Donato Donati، نويسنده , , Wayne C. Hayes، نويسنده , , Claire Martin، نويسنده , , Patrick J. Murphy، نويسنده , , Fabio Ponticelli، نويسنده , , Jessica K. Melville-Richards، نويسنده ,
Abstract :
UV irradiation of hitherto unknown 4,5-bis-benzo[b]thiophen-3-yl-[1,3]dithiol-2-one gave 3-(3-benzo[b]thienyl)-thieno[3,4-c]benzo[e][1,2]dithiine by loss of carbon monoxide and rearrangement, whereas 4,5-bis-(2-bromo-phenyl)-[1,3]dithiol-2-one gave a polymeric material containing S–S bridges. The structures of both photoproducts were demonstrated on the basis of chemical behaviour and/or X-ray diffraction.