Title of article
Straightforward and highly efficient catalyst-free regioselective reaction of thiol to β-nitrostyrene: a concise synthesis of vinyl sulfide and nitro sulfide
Author/Authors
Cheng-Ming Chu، نويسنده , , Zhijay Tu، نويسنده , , Pohsi Wu، نويسنده , , Chieh-Chieh Wang، نويسنده , , Ju-Tsung Liu، نويسنده , , Chunwei Kuo، نويسنده , , Yu-Hsuan Shin، نويسنده , , Ching-Fa Yao، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
8
From page
3878
To page
3885
Abstract
Under catalyst-free reaction conditions, solvent-mediated addition of thiol 2 to β-nitrostyrene 1 proceeded with regioselective control to afford either adduct 3 or vinyl sulfide 4 in good to excellent yield. Thermodynamic and autocatalytic reaction mechanisms were proposed to rationalize the products thus formed.
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1095402
Link To Document