Title of article
Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of β,γ-unsaturated ketones
Author/Authors
Helen E. Randell-Sly، نويسنده , , James D. Osborne، نويسنده , , Robert L. Woodward، نويسنده , , Gordon S. Currie، نويسنده , , Michael C. Willis، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
8
From page
5110
To page
5117
Abstract
A variety of β-S-substituted aldehydes undergo efficient and regioselective rhodium catalyzed hydroacylation reactions with 1,3-disubstituted and 1,1,3-trisubstituted allenes, to deliver β,γ-unsaturated ketone products. Regioselectivites are controlled primarily by steric factors. The reactions are catalyzed by the complex [Rh(dppe)]ClO4.
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097137
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