Cycloaddition of allylsilanes. Part 20: Organosilicon-mediated total synthesis of (±)-cameroonanol
Author/Authors :
Arndt W. Schmidt، نويسنده , , Thomas Olpp، نويسنده , , S?ren Schmid، نويسنده , , Anne J?ger، نويسنده , , Hans-Joachim Kn?lker، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Pages :
7
From page :
5484
To page :
5490
Abstract :
We describe a seven-step total synthesis of the triquinane sesquiterpene (±)-cameroonanol using a Lewis acid-promoted [3+2] cycloaddition of an allylsilane and a modified Fleming–Tamao oxidation as key reactions.
