Title of article
O-Arylsulfonyl hydroxylamines via a decarboxylative rearrangement
Author/Authors
Stefania Fioravanti، نويسنده , , Lucio Pellacani، نويسنده , , Paolo A. Tardella، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
5
From page
5747
To page
5751
Abstract
(E)-O-Arylsulfonyl-N-(2-nitroalk-2-enyl)hydroxylamines were easily obtained in good yields starting from (E)-nitro allylic alcohols, the crucial step being an inorganic base-catalyzed decarboxylative rearrangement of proposed labile unsaturated carbamates. A possible mechanism for the outcome of the reaction, characterized by the unusual retention of the sulfonyloxy group, is proposed.
Keywords
Inorganic bases , Decarboxylation reaction , Nitro allylic alcohols , hydroxylamines
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097280
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