Author/Authors :
Ryan Hart، نويسنده , , Pamela Pollet، نويسنده , , Dominique J. Hahne، نويسنده , , Ejae John، نويسنده , , Veronica Llopis-Mestre، نويسنده , , Vittoria Blasucci، نويسنده , , Hillary Huttenhower، نويسنده , , Walter Leitner، نويسنده , , Charles A. Eckert، نويسنده , , Charles L. Liotta، نويسنده ,
Abstract :
Reversible ionic liquids are a novel class of solvents that combine an effective medium where reactions occur with a ‘built-in’ separation ability for facile recovery of the products and catalysts, making the solvent available for recycle. We report the utility of these solvents in a number of reactions (Claisen–Schmidt condensation, Heck C–C coupling, and CO2 capture) and discuss the effectiveness of the separation. We also provide insight into the challenges and limitations of using these unique solvent systems to couple reactions and separations.
