Title of article :
Unexpected formation of oxetanes from a geminal difluorinated δ-lactone
Author/Authors :
René Csuk، نويسنده , , Erik Prell، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Pages :
6
From page :
1313
To page :
1318
Abstract :
A perbenzylated 3,3-difluorinated hexono-1,5-lactone was prepared in several steps. Reaction of this lactone with MeOH/p-TsOH followed by a treatment with ion-exchange resin led to the formation of an exocyclic oxetane derived vinylether. Similar reaction with ammonia gave the corresponding carboxamido substituted oxetane in good yields.
Keywords :
Carbohydrate , Difluorination , Ring contraction , Oxetane
Journal title :
Tetrahedron
Serial Year :
2010
Journal title :
Tetrahedron
Record number :
1100552
Link To Document :
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