• Title of article

    Gas-phase pyrolysis of benzimidazole derivatives: novel route to condensed heterocycles

  • Author/Authors

    Maher R. Ibrahim، نويسنده , , Talal F. Al-Azemi، نويسنده , , Alya Al-Etabi، نويسنده , , Osman M.E. El-Dusouqui، نويسنده , , Nouria A. Al-Awadi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2010
  • Pages
    8
  • From page
    4243
  • To page
    4250
  • Abstract
    Gas-phase pyrolysis of N-(1H-benzimidazol-2-yl)-N′-arylidenehydrazines 1a–e gave the corresponding arylnitriles 2a–e, 2-aminobenzimidazole 3, 2,4,5-triphenylimidazole 4, 1,3-diphenyl-8H-2,3a,8-triazacyclopenta[a]indene 5, and 5,11-diphenyl-6H,12H-dibenzimidazo[1,2-a];1’,2’-d]pyrazine 6. The kinetics and analysis of the products of reaction are reported and used to elucidate the mechanism of the elimination process.
  • Keywords
    Benzimidazol-2-yl-N?-arylidenehydrazine , 2-Aminobenzimidazole , 2-b]fluorine , mechanism , Gas-phase pyrolysis
  • Journal title
    Tetrahedron
  • Serial Year
    2010
  • Journal title
    Tetrahedron
  • Record number

    1100901