Title of article
Synthesis and properties of BCOD-fused trithiasapphyrin and trithiabenzosapphyrins
Author/Authors
Tetsuo Okujima، نويسنده , , Tasuku Kikkawa، نويسنده , , Saori Kawakami، نويسنده , , Yusuke Shimizu، نويسنده , , Hiroko Yamada، نويسنده , , Noboru Ono، نويسنده , , Hidemitsu Uno، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
6
From page
7213
To page
7218
Abstract
Bicyclo[2.2.2]octadiene(BCOD)-fused trithiasapphyrin was prepared by 3+2 condensation of BCOD-fused thiatripyrrane with BCOD-fused bithiophene. The BCOD-fused trithiasapphyrin was successfully converted to pentabenzo[b,g,l,q,v]sapphyrin by the thermal retro-Diels–Alder reaction. In this case, trithiapentabenzo[b,g,l,q,v]- and trithiadibenzo[g,q]sapphyrins were selectively prepared by control of the temperature in the thermal retro-Diels–Alder reaction.
Keywords
Core-modified sapphyrin , Benzosapphyrin , 22? Electron circuit , retro-Diels–Alder reaction
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1101253
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