Title of article :
gem-Bromochlorospiropentane reactivity toward methyllithium: an unusual carbenoid rearrangement
Author/Authors :
Kseniya N. Sedenkova، نويسنده , , Elena B. Averina، نويسنده , , Yuri K. Grishin، نويسنده , , Tamara S. Kuznetzova، نويسنده , , Nikolai S. Zefirov، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
A skeletal carbenoid rearrangement of the gem-bromochlorospiropentanes in the presence of methyllithium has been studied. The synthetic and mechanistic aspects of this rearrangement as well as the influence of the halogen atom nature on the reaction pathway are discussed.
Keywords :
carbenoids , Methyllithium , Halogenocyclobutenes , Spiro compounds , gem-Dihalogenospiropentanes
Journal title :
Tetrahedron
Journal title :
Tetrahedron
