Title of article :
Further studies on vinamidinium salt amine exchange reactions, borohydride reductions, and subsequent transformations
Author/Authors :
John T. Gupton، نويسنده , , Nakul Telang، نويسنده , , Xin Jia، نويسنده , , Benjamin C. Giglio، نويسنده , , James E. Eaton، نويسنده , , Peter J. Barelli، نويسنده , , Mona Hovaizi، نويسنده , , Kayleigh E. Hall، نويسنده , , R. Scott Welden، نويسنده , , Matthew J. Keough، نويسنده , , Eric F. Worrall، نويسنده , , Kara L. Finzel، نويسنده , , Emily J. Kluball، نويسنده , , René P.F Kanters، نويسنده , , Timothy M. Smith، نويسنده , , Stanto، نويسنده ,
Abstract :
Studies directed at the amine exchange reaction of vinamidinium salts followed by sodium borohydride reduction to secondary and tertiary allylic amines are described. The tertiary allylic amines were alkylated and subjected to base mediated rearrangement to yield a variety of highly functionalized tertiary homoallylic amines.
Keywords :
allylic amine , Reduction , 2 , Vinamidinium salt , 3-sigmatropic rearrangement
