Title of article
PhI(OAc)2-mediated iminobromination for synthesis of bromomethyl cyclic imines starting from alkenyl carbonitriles and Grignard reagents
Author/Authors
Stephen Sanjaya، نويسنده , , Shunsuke Chiba، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
7
From page
590
To page
596
Abstract
PhI(OAc)2-mediated iminobromination was developed starting from alkenyl carbonitriles and Grignard reagents. The present transformation is carried out by a sequence of nucleophilic addition of Grignard reagents to alkenyl carbonitriles to form N–H imines and their iminohalogenation by subsequent treatment with PhI(OAc)2.
Keywords
Bromomethyl cyclic imines , Alkenyl carbonitriles , Grignard reagents , PhI(OAc)2 , Iminobromination
Journal title
Tetrahedron
Serial Year
2011
Journal title
Tetrahedron
Record number
1102861
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