Title of article :
Synthesis of 2(5H)-Furanones via Oxidative Ring Expansion of 4Hydroxy-2-cyclobutenones
Author/Authors :
Kimpe، Norbert De نويسنده , , Verniest، Guido نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
A new method to reduce cyclobutenediones towards 4-hydroxy-2cyclobutenones was established. The latter compounds gave rise to new 5halo-2(5H)-furanones by reaction with halogenating agents via a cationic ring-opening-ring-closure mechanism.
Keywords :
cyclobutenones , 2(5H)-furanones , Oxidations , ring expansion , Rearrangements