Title of article
First total syntheses of bicyclic marine sesquiterpenoids drechslerines A and B
Author/Authors
Hisahiro Hagiwara، نويسنده , , Masakazu Fukushima، نويسنده , , Kimihiko Kinugawa، نويسنده , , Takuya Matsui، نويسنده , , Takashi Hoshi، نويسنده , , Toshio Suzuki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
8
From page
4061
To page
4068
Abstract
The first total syntheses of the bicyclic sesquiterpenoids drechslerines A (1) and B (2), which were isolated from the algicolous fungus Drechslera dematioidea in the marine red alga Liagora viscida, has been accomplished starting from (S)-carvone (13) via three palladium-catalyzed reactions, namely, diastereoselective allylation, conjugate reduction, and carbon monoxide insertion, as the key reactions.
Keywords
Bicyclic alicyclic compounds , Diastereoselective allylation , sesquiterpenoid , Drechslerine , Carbon monoxide insertion
Journal title
Tetrahedron
Serial Year
2011
Journal title
Tetrahedron
Record number
1103270
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