Title of article :
Highly Efficient and Regioselective Synthesis of 1,1-Bis(alkoxy dimethylsilyl)ethenes
Author/Authors :
Marciniec، Bogdan نويسنده , , Pawluc، Piotr نويسنده , , Hreczycho، Grzegorz نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
New 1,1-bis(alkoxydimethylsilyl)ethenes have been readily synthesized via ruthenium-hydride complex catalyzed selective silylative coupling cyclization of N,N’-dimethyl-N,N’-bis(dimethylvinylsilyl)ethane-1,2-diamine to yield 1,2,2,4,4,5-hexamethyl-3-methylene-1,5-diaza-2,4disilacycloheptane, which then undergoes reaction with various alcohols.
Keywords :
1,1-bis(silyl)ethenes , silylative coupling , cyclic silaalkenes , silylamines , ruthenium-hydride complexes
