Title of article :
One-Pot Synthesis of E-Alkylidene Derivatives of 3H-Furan-2-ones from 4-Pentynoic Acid and Aldehyde
Author/Authors :
Jun، Chul-Ho نويسنده , , Lim، Sung-Gon نويسنده , , Kwon، Bong-Il نويسنده , , Choi، Moon-Gun نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
4-Pentynoic acid reacts with aldehyde under the co-catalyst system of Wilkinson’s complex and 2-aminopyridine to give E-alkylidene derivatives of 3H-furan-2-one through the transition metal-catalyzed cyclization of 4pentynoic acid followed by condensation of the resulting lactone with aldehyde.
Keywords :
lactone , lactam , Wilkinson’s complex , ALDEHYDE , 4-pentynoic acid