Title of article :
Concise stereoselective synthesis of marine sesterterpene, 16-deacetoxy-12-epi-scalarafuran acetate and its 14-epimer via intramolecular Diels–Alder addition
Author/Authors :
Zheng-Lin Wang، نويسنده , , Zi-Gang Zhang، نويسنده , , Hong-Chang Li، نويسنده , , Wei-Ping Deng، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Pages :
5
From page :
6939
To page :
6943
Abstract :
The stereoselective synthesis of C12 oxygenated marine scalaranic sesterterpene 16-deacetoxy-12-epi-scalarafuran acetate and its 14-epimer were described. A highly stereoselective intramolecular Diels–Alder addition was designed as the key step to construct the ring D, and the absolute configurations of natural 16-deacetoxy-12-epi-scalarafuran acetate was supported by the X-ray diffraction analysis of single crystal of corresponding 16-deacetoxy-12-epi-scalarafuran.
Journal title :
Tetrahedron
Serial Year :
2011
Journal title :
Tetrahedron
Record number :
1103624
Link To Document :
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