Author/Authors :
Wonjae Lee، نويسنده , , Seth E. Snyder، نويسنده , , Phillip I. Volkers، نويسنده , , William H. Pirkle، نويسنده , , David A. Engebretson، نويسنده , , William A. Boulanger، نويسنده , , Huei-Shian Lin، نويسنده , , Bin-Syuan Huang، نويسنده , , James R. Carey، نويسنده ,
Abstract :
Chiral stationary phases were synthesized and their ability to separate racemic precursors from which they were derived was assessed. Taken in conjunction with homochiral recognition previously observed in the solid state, the results of this study reveal that a geometrically controlling π–π interaction has a profound influence on molecular recognition.
Keywords :
Homochiral , molecular recognition , Chiral stationary phases , Self-assembly , ?–? interaction