Author/Authors :
Jean-Yves Balandier، نويسنده , , Florence Quist، نويسنده , , Noham Sebaihi، نويسنده , , Claude Niebel، نويسنده , , Benoît Tylleman، نويسنده , , Pol Boudard، نويسنده , , Saïd Bouzakraoui، نويسنده , , Vincent Lemaur، نويسنده , , Jérôme Cornil، نويسنده , , Roberto Lazzaroni، نويسنده , , Yves Henri Geerts، نويسنده , , Sara Stas، نويسنده ,
Abstract :
The synthesis and characterization of two new anthradithiophene (ADT) derivatives bearing electron donating (triphenylamine) or accepting (5-formylthiophen-2-yl unit) moieties have been performed to assess their potential as materials for organic photovoltaics. Optical spectroscopy was used to evaluate the effect of electron rich/poor substituents on the visible absorption spectrum and on the stability towards photo-oxidation. The results are interpreted with the assistance of quantum-chemical calculations and cyclic voltammetry experiments.
Keywords :
Cyclic voltammetry , Stability studies , Organic electronics , Anthradithiophene , Donor/acceptor systems