• Title of article

    The reaction of optically active α-aminocarboxylic acid hydrazides with triethyl orthoesters

  • Author/Authors

    Agnieszka Kudelko، نويسنده , , Wojciech Zieli?ski، نويسنده , , Krzysztof Ejsmont، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2011
  • Pages
    8
  • From page
    7838
  • To page
    7845
  • Abstract
    New derivatives of 2-(1-amino-1-phenylmethyl)-1,3,4-oxadiazole and 1,2,4-triazin-6-one were synthesised in the reactions of optically active α-aminocarboxylic acid hydrazides and triethyl orthoesters in xylene. The electronic and steric effects of substituents at the α position influencing the formation of five- or six-membered products are discussed.
  • Keywords
    Lanthanide shift reagent , 4-Triazin-6-one , 2 , ?-Aminocarboxylic acid hydrazide , racemisation , 2-Aminomethyl-1 , 3 , pKa Ionisation constant , 1 , 4-oxadiazole , Synthesis
  • Journal title
    Tetrahedron
  • Serial Year
    2011
  • Journal title
    Tetrahedron
  • Record number

    1103729