Title of article
Cu-deposits on Mg metal surfaces promote electron transfer reactions
Author/Authors
Shinya Utsumi، نويسنده , , Toshimasa Katagiri، نويسنده , , Kenji Uneyama، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
7
From page
1085
To page
1091
Abstract
The enhancement of the electron transfer processes in the Grignard reagent formation-type ring silylation and the defluorination–silylation of perfluoroalkyl benzenes by Cu(0)-deposited Mg metal were confirmed. Microscopic analysis and substituent effects implied a different reduction process in the presence of Cu-deposited Mg metal than in the presence of bare Mg metal.
Keywords
Grignard reagent formation-type silylation , Copper-deposited magnesium , Electron transfer , Selective dehalogenation , Reductive defluorination
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104138
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