Title of article
O- and N-Glycosidation of d-glycals using Ferrier rearrangement under Mitsunobu reaction conditions. Application to N-nucleoside synthesis
Author/Authors
Kyosuke Michigami، نويسنده , , Masahiko Hayashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
5
From page
1092
To page
1096
Abstract
We have disclosed the reaction of 3-hydroxy free glycals with O- or N-nucleophiles under Mitsunobu reaction conditions proceeded to produce 2,3-unsaturated glycosides in good to high yield and moderate stereoselectivity. The reaction would take place via allyloxycarbenium ion.
Keywords
Ferrier reaction , O-Glycosidation , N-Glycosidation , Glycal , Mitsunobu reaction
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104139
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