Title of article :
Preparation of Magnesium Enolates of (alpha)-Keto Esters and Synthetic Applications
Author/Authors :
Grison، Claude نويسنده , , Petek، Sylvain نويسنده , , Coutrot، Philippe نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The reaction between (alpha)-chloroglycidic esters 1 and magnesium iodide in the presence of an excess of active magnesium led to magnesium (alpha)-ketoester enolates 3. Some synthetic applications of these new reagents are reported.
Keywords :
pyruvic ester , (alpha)-keto esters , (alpha)-chloroglycidic esters , magnesium enolate , (beta)-iodo-(alpha)-ketoesters
