Title of article
Reactions of 4-ethoxy-1,1,1-trifluorobut-3-en-2-one with diethyl malonate anion: synthesis and crystal structures of fluorinated organo alkali–metal complexes
Author/Authors
Tao Song، نويسنده , , Lei Liu، نويسنده , , Jingwei Zhao، نويسنده , , Huiling Jiang، نويسنده , , Shizheng Zhu، نويسنده , , Liangzhong Xu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
6
From page
5677
To page
5682
Abstract
At room temperature, 4-ethoxy-1,1,1-trifluorobut-3-en-2-one reacted with alkali metal salts of diethyl malonate to give two kinds of complexes. One is the solvent molecule-involved complexes, and the other is a sheer ion aggregates composed by alkali metal cation and carbanion. Both crystals are fully characterized by spectroscopic methods and single crystal X-ray diffraction analyses.
Keywords
Alkali metal , 1 , 1-trifluorobut-3-en-2-one , 1 , 3-dicarbonyl compound , Coordination crystal , Solvent influence , 4-Ethoxy-1
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104685
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