Title of article :
Toward the synthesis of γ-pyrone-containing natural products: diastereoselective aldol-type reaction of a γ-pyrone
Author/Authors :
Takuma Takemura، نويسنده , , Jun-ichiro Hayakawa، نويسنده , , Emi Fukasawa، نويسنده , , Tetsuya Sengoku، نويسنده , , Hideo Kigoshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
The diastereoselective aldol-type reaction of a γ-pyrone via a sodium anion has been developed. This reaction is useful for synthesizing γ-pyrone-containing natural products. Also, we applied the Mukaiyama aldol-type reaction of silyl enol ether of γ-pyrone by using TiCl4. This Mukaiyama aldol-type reaction of γ-pyrone indicated higher anti-aldol selectivity than the aldol-type reaction of a γ-pyrone with NaHMDS.
Keywords :
Mukaiyama aldol-type reaction of a ?-pyrone , anti-Aldol selectivity , Diastereoselective aldol-type reaction of a ?-pyrone
Journal title :
Tetrahedron
Journal title :
Tetrahedron
