Title of article
Highly Regio- and Stereoselective Hydrostannylation of Propargyl Alcohols and Ethers Using Dibutylchlorostannane and Lithium Chloride
Author/Authors
Miura، Katsukiyo نويسنده , , Hosomi، Akira نويسنده , , Wang، Di نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-405
From page
406
To page
0
Abstract
In the presence of LiCl, dibutylchlorostannane (Bu2SnClH) reacted with (gamma)unsubstituted propargyl alcohols and ethers to give (gamma)-stannylated allyl alcohols and ethers, respectively, with high regio- and stereoselectivity. These vinylstannane products could be successfully utilized for the Pdcatalyzed cross-coupling reaction.
Keywords
radical reactions , alcohols , Alkynes , cross-coupling , hydrostannations
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110488
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