Title of article
Influence of bromide ions on the synthesis of anomeric thiocyanates
Author/Authors
Piotr Cmoch، نويسنده , , Zbigniew Pakulski، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
6
From page
7435
To page
7440
Abstract
The synthesis of anomeric thiocyanates with the α- and β-configuration is described. Reactions performed under standard conditions afforded the 1,2-trans derivatives as the main products, whereas in the presence of the quaternary ammonium salts, the 1,2-cis-thiocyanates were formed preferentially. The strong influence of the bromide ions on the distribution of the products is discussed.
Keywords
Anomeric thiocyanates , Influence of bromide ions , Equilibration
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104880
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