Title of article :
Enantiodivergent synthesis of (+)- and (−)-isolaurepan
Author/Authors :
Gonzalo Pazos، نويسنده , , Manuel Pérez، نويسنده , , Zoila G?ndara، نويسنده , , Generosa G?mez، نويسنده , , Yagamare Fall، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
The enantiodivergent synthesis of (+)-and (−)-isolaurepan was achieved from a common chiral template easily available from tri-O-acetyl-d-glucal, using as key step a diastereoselective thermal Claisen rearrangement, combined with a ring expansion reaction using trimethylsilyldiazomethane.
Keywords :
Marine toxins , Claisen rearrangement , 2 , 6-syn-Disubstituted tetrahydropyrans , Enantioselective synthesis
Journal title :
Tetrahedron
Journal title :
Tetrahedron
