Title of article
Iridium-Catalyzed Oxidative Dimerization of Primary Alcohols to Esters Using 2-Butanone as an Oxidant
Author/Authors
Suzuki، Takeyuki نويسنده , , Matsuo، Tomohito نويسنده , , Watanabe، Kazuhiro نويسنده , , Katoh، Tadashi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1452
From page
1453
To page
0
Abstract
Oxidative dimerization of primary alcohols with 2-butanone in the presence of an amino alcohol-based Ir bifunctional catalyst was accomplished for the first time. The reaction proceeds with 1-2 mol% of the catalyst and 0.3 mol equivalents of K2CO3 in 2-butanone at room temperature to give the corresponding dimeric esters in 30-93% yield.
Keywords
esters , alcohols , hydrogen transfer , iridium catalyst , oxidative dimerization
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110511
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