Title of article
Iridium-catalyzed enantioselective allylation of sodium 2-aminobenzenethiolate: an access to chiral benzo-fused N,S-heterocycles
Author/Authors
Ning Gao، نويسنده , , Xinwen Guo، نويسنده , , Sheng-Cai Zheng، نويسنده , , Weikang Yang، نويسنده , , Xiao-Ming Zhao، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
6
From page
9413
To page
9418
Abstract
The use of sodium 2-aminobenzenethiolate in the enantioselective iridium catalyzed allylic substitution with a range of methyl allyl carbonates allows the concise synthesis of the branch-type products with both excellent regio- and enantioselectivities, which are functionalized N,S-containing allylic intermediates for the formation of chiral benzo-fused N,S-heterocycles.
Keywords
Allylation , phosphoramidite ligand , Iridium , Sodium 2-aminobenzenethiolate , S-heterocycle , Benzo-fused N
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1105122
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