Title of article
Trifluoroacetic acid catalyzed dibenzodiazocine synthesis: optimization and mechanism study
Author/Authors
Na Zhao، نويسنده , , Li Qiu، نويسنده , , Xiao Wang، نويسنده , , Jianzhong Li، نويسنده , , Yi Jiang، نويسنده , , Xiaobo Wan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
7
From page
9665
To page
9671
Abstract
Dibenzo[b,f][1,5]diazocines, a class of potential building blocks for novel electrochemical actuators, were synthesized via a novel, efficient acid-catalyzed reaction of 2-acylbenzoisocyanate at room temperature. Real-time NMR analysis and the captured intermediate showed the mechanism was an unprecedented cyclization of the isocyanate with the neighboring acyl group, followed by the dimerization.
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1105149
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