Title of article
Palladium-catalyzed vinylselenation of allenes
Author/Authors
Shin-ichi Fujiwara، نويسنده , , Maiko Okuyama، نويسنده , , Susumu Tsuda، نويسنده , , Takanori Iwasaki، نويسنده , , Hitoshi Kuniyasu، نويسنده , , Nobuaki Kambe، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
7
From page
10523
To page
10529
Abstract
Pd(0)-catalyzed vinylselenation of allenes was found to proceed efficiently in the presence of P(p-MeC6H4)3 as a ligand to afford the corresponding 2-selenomethyl-1,3-dienes. This reaction is highly regioselective and vinyl selenides added to the terminal double bond of the allenes exclusively to introduce the vinyl group at the inner carbon and the selenium moiety at the terminal carbon. The stereochemistry of the double bond of the vinyl selenides was perfectly retained.
Keywords
Vinylselenation , 3-diene , Allene , Vinyl selenide , Pd catalyst , 1
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1105244
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